Sep. 26, 2013 — Ever since the Bronze Age, metals have been cast in different shapes for different applications. Smooth surfaces that are resistant to corrosion are crucial for many of the present-day uses of cast metals, ranging from bio-implants to automotive parts. Yingchun Guan, from the A*STAR Singapore Institute of Manufacturing Technology (SIMTech) and her co-workers have shown how different laser-processing methods improve metal surfaces and protect them against corrosion.
Laser processing involves scanning a high-intensity laser beam multiple times across the surface of a metal. Each scan by the laser beam 'writes' a track in the surface, which partially melts the metal. Consecutive tracks can overlap -- the degree to which affects how well the melting caused by these tracks will smooth the surface of the metal. The scanning speed can also affect the surface melt.
Guan and co-workers investigated how different degrees of overlap between the tracks affect the surface properties of AZ91D -- a common magnesium alloy. "AZ91D is the most widely used magnesium alloy for the production of high-volume components for the automotive, electronics and telecommunications industries," Guan explains.
By examining cross-sections of AZ91D samples post-melt, the researchers found that the greater the degree of overlap between the tracks, the fewer the number of small cracks that developed during solidification (see image). According to Guan, this finding should be considered when processing metals destined for exposure to fluids, such as those that will be used in bio-implants.
The researchers also detected alterations in the alloy's composition through changes in the degree of laser-track overlap. Melted magnesium evaporates more readily than aluminum, and as the degree of laser-track overlap increased, it changed the composition of the alloy -- particularly in the larger areas of melt. Theoretical calculations by Guan and her co-workers described these kinetics accurately.
According to the team's model, a greater level of overlap provided a greater amount of heat, which improved the convection of the metals within the molten liquid and yielded a more homogeneous surface. Electrochemical tests by the team also confirmed that the more homogeneous the surface of a material, the more resistant it was to corrosion.
The team's approach, particularly the theoretical model, is applicable to assess laser processing of other alloys and compounds, Guan notes. As the surface structures affect not only the mechanical and chemical properties but also the electronic, thermal and optical parameters, these findings will be of relevance to metals used in a variety of applications.
Tell us what you think of Chemistry 2011 -- we welcome both positive and negative comments. Have any problems using the site? Questions?