Scientists at the University at Buffalo think so.
BODIPY — short for boron-dipyrromethene — shines brightly in the dark under a black light.
But the traits that facilitate Energy-Storage'>energy storage are less visible. According to new research, the dye has unusual chemical properties that enable it to excel at two key tasks: storing electrons and participating in electron transfer. Batteries must perform these functions to save and deliver energy, and BODIPY is very good at them.
In experiments, a BODIPY-based test battery operated efficiently and with longevity, running well after researchers drained and recharged it 100 times.
“As the world becomes more reliant on alternative energy sources, one of the huge questions we have is, 'How do we store energy?’ What happens when the sun goes down at night, or when the wind stops?” says lead researcher Timothy Cook, PhD, an assistant professor of chemistry in the University at Buffalo College of Arts and Sciences. “All these energy sources are intermittent, so we need batteries that can store enough energy to power the average house.”
A dye-based battery of the future
Lithium-ion batteries, for example, are risky in that they can catch fire if they break open, Cook says. The dye-based batteries would not have this problem; if they ruptured, they would simply leak, he says.
Redox flow batteries can also be easily enlarged to store more energy — enough to allow a homeowner to power a solar house overnight, for instance, or to enable a utility company to stockpile wind energy for peak usage times. This matters because scaling up has been a challenge for many other proposed battery technologies.
How BODIPY works in a battery
Redox flow batteries consist of two tanks of fluids separated by various barriers.
When the battery is being used, electrons are harvested from one tank and moved to the other, generating an electric current that — in theory — could power devices as small as a flashlight or as big as a house. To recharge the battery, you would use a solar, wind or other energy source to force the electrons back into the original tank, where they would be available to do their job again.
“The library of molecules used in redox flow batteries is currently small but is expected to grow significantly in coming years,” Cook says. “Our research identifies BODIPY dye as a promising candidate.”
Within this cocktail, the BODIPY compounds displayed a notable quality: They were able to give up and receive an electron without degrading as many other chemicals do. This trait enabled the dye to store electrons and facilitate their transfer between the battery’s two ends during repeated cycles — 100 — of charging and draining.
Based on the experiments, scientists also predict that BODIPY batteries would be powerful enough to be useful to society, generating an estimated 2.3 volts of electricity.
The research team included first author Anjula M. Kosswattaarachchi, a UB chemistry PhD student, and Alan Friedman, PhD, a UB research assistant professor in chemistry. The study was funded by UB, The Research Foundation for The State University of New York, and the National Center for Research Resources, part of the National Institutes of Health.
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