Chemistry 2011.org
Chemistry2011.org
All About Chemistry... 2011 and beyond

Related Stories

High temp superconductivity: You can't play checkers with charge ordering

CIFAR fellows were among physicists who observed the shape of a strange phenomenon that interferes with high-temperature superconductivity called charge ordering, discovering that it is stripy, not checkered, and settling a long-standing debate in the field.

Charge ordering creates instability in some metals at temperatures warmer than about -100 degrees Celsius, causing some electrons to reorganize into new periodical static patterns competing with superconductivity. But scientists wonder if it may also play an essential role in propelling electrons into the tight pairs that allow them to travel without resistance.

In order to understand what charge ordering does, and whether it's a hindrance, a help, or a bit of both, scientists must first understand what it is -- starting with its shape.

Riccardo Comin, lead author on a new paper in Science, set out to determine whether the pattern of charge ordering was a checkerboard or a series of stripes by x-raying very cold yttrium barium copper oxide. His collaborators at the Quantum Matter Institute of the University of British Columbia included CIFAR Global Scholar Eduardo da Silva Neto and senior fellows of the Quantum Materials program Ruixing Liang, Walter Hardy, Doug Bonn, George Sawatzky, and Andrea Damascelli -- who is Comin's PhD supervisor and team leader of this study.

They found the pattern is striped, meaning the electrons self-organize along one direction (1D), rather than in two directions (2D) as they would in a checkerboard pattern. However, when the temperature cools down far enough, charge ordering dies off and superconductivity takes over, allowing electrons to travel freely with no resistance, no longer constrained to one dimension.

The result is exciting because physics is much more interesting in low dimension, says Damascelli. And in the cuprates these 1D patterns are realized within the 2D Cu-O planes, which already con-strain the motion of electron to less than 3D, even before charge ordering sets in.

"Superconductivity in conventional 3D metals is limited to a Tc of few degrees Kelvin," he says, citing examples such as aluminum and niobium. "High temperature superconductors are quasi 2D metals, and now with a tendency toward 1D electronic ordering."

Furthermore, the researchers found that charge ordering competes with superconductivity much more strongly along one direction than the other. The results are an important step in knowing what drives superconductivity and what my hinder it.

"Is charge ordering just an anomaly, or is it there in all these systems because there is an underlying interaction which isn't completely removed from superconductivity?" Comin asks. "The two phenomena are competing but in a sense they're also interconnected."

Damascelli says the material in this study, yttrium barium copper oxide, is the superstar of copper-oxides because of its exquisite purity and high transition temperature. It's also a Canadian success story -- CIFAR fellows Liang-Bonn-Hardy are leading growers and suppliers of the crystal for re-search the world over. "That's why the Canadian groups and in particular the CIFAR program has had such an impact, because we had access to the best materials," Damascelli says.

Story Source:

The above story is based on materials provided by Canadian Institute for Advanced Research. Note: Materials may be edited for content and length.

Share this story with your friends!

Social Networking

Please recommend us on Facebook, Twitter and more:

Other social media tools

Global Partners
Feedback

Tell us what you think of Chemistry 2011 -- we welcome both positive and negative comments. Have any problems using the site? Questions?

About us

Chemistry2011 is an informational resource for students, educators and the self-taught in the field of chemistry. We offer resources such as course materials, chemistry department listings, activities, events, projects and more along with current news releases.

Events & Activities

Are you interested in listing an event or sharing an activity or idea? Perhaps you are coordinating an event and are in need of additional resources? Within our site you will find a variety of activities and projects your peers have previously submitted or which have been freely shared through creative commons licenses. Here are some highlights: Featured Idea 1, Featured Idea 2.

About you

Ready to get involved? The first step is to sign up by following the link: Join Here. Also don’t forget to fill out your profile including any professional designations.

Global Partners